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Dr Adrián Gómez Suárez

Organic Chemistry
Bergische Universität Wuppertal
Gaußstr. 20
42119 Wuppertal
Germany


Office: Building V, room 10.019

Tel.: +49 (0)202 439 2775  
Fax: +49 (0)202 439 2648

e-mail: gomezsuarez@uni-wuppertal.de

BUW Publications

2021

5. Synthesis of γ-oxo-α-amino acids via radical acylation with carboxylic Acids

K. Merkens,† F.J. Aguilar Troyano,† K. Anwar, A. Gómez-Suárez* ChemRxiv (†These authors contributed equally)

4. Radical‐Based Synthesis and Modification of Amino Acids

F.J. Aguilar Troyano,† K. Merkens,† K. Anwar, A. Gómez-Suárez* Angew. Chem. Int. Ed. 2021, 60, 1098-1115. (†These authors contributed equally)

2020

3. Selectfluor® Radical Dication (TEDA2+·) – A Versatile Species in Modern Synthetic Organic Chemistry

F.J. Aguilar Troyano,† K. Merkens,† A. Gómez-Suárez* Asian J. Org. Chem 2020, 9, 992-1007. (†These authors contributed equally)

2. Synthesis of Unnatural alpha-Amino Acid Derivatives via Light-mediated Radical Decarboxylative Processes

K. Merkens,† F.J. Aguilar Troyano,† J. Djossou, A. Gómez-Suárez* Adv. Synth. Catal. 2020, 362, 2354-2359 (†These authors contributed equally)

Synfact Highlight

OPR&D – Highlights from the literature

2019

1. Light‐mediated Formal Radical Deoxyfluorination of Tertiary Alcohols via Selective Single Electron Oxidation with TEDA2+·

F.J. Aguilar Troyano, F. Ballaschk,† M. Jaschinski,† Y. Ozkaya,† A. Gómez-Suárez* Chem. Eur. J. 2019, 25, 14054 (†These authors contributed equally)

Doctoral & Postdoctoral Publications

28. Discovery of Unforeseen Energy-Transfer-Based Transformations Using a Combined Screening Approach

F. Strieth-Kalthoff, C. Henkel, M. Teders, A. Kahnt, W. Knolle, A. Gómez-Suárez, K. Dirian, W. Alex, K. Bergander, C. G. Daniliuc, B. Abel, D. M. Guldi, F. Glorius, Chem. 2019, 5, 2183

27. The energy-transfer-enabled biocompatible disulfide–ene reaction

M. Teders, C. Henkel, L. Anhäuser, F. Strieth-Kalthoff, A. Gómez-Suárez, R. Kleinmans, A. Kahnt, A. Rentmeister, D. Guldi, F. Glorius, Nat. Chem. 2018, 10, 981.

26. Quantifying and understanding the steric properties of N-heterocyclic carbenes;

Gómez-Suárez, A.; Nelson, D. J.; Nolan, S. P., Chem. Commun. 2017, 53, 2650

 

 

25. Diverse visible light-promoted functionalizations of benzotriazoles inspired by mechanism-based luminescence screening

Teders, M.; Gómez-Suárez, A.+; Pitzer, L.+; Hopkinson, M. N.; Glorius, F., Angew. Chem. Int. Ed. 2016, 56, 902. +Both authors contributed equally.

24. A switchable gold catalyst by encapsulation in a self-assembled cage

Jans, A.; Gómez-Suárez, A.; Nolan, S. P.; Reek, J. N. H., Chem, Eur. J. 2016, 22, 14836

23. Catalytic access to alkyl bromides, chlorides and iodides via visible light-promoted decarboxylative halogenation

Candish, L.+; Standley, E. A.+; Gómez-Suárez, A.; Mukherjee, S.; Glorius, F., Chem, Eur. J. 2016, 22, 9971.

+Both authors contributed equally.

22. Accelerated discovery in photocatalysis using a mechanism-based screening method

Hopkinson, M. N.; Gómez-Suárez, A.; Teders, M.; Sahoo, B.; Glorius, F., Angew. Chem. Int. Ed. 2016, 55, 4361

21. Visible light-promoted decarboxylative di- and trifluoromethylthiolation of alkyl carboxylic acids

Candish, L.+; Pitzer, L.+; Gómez-Suárez, A.; Glorius, F., Chem, Eur. J. 2016, 22, 4753.

+Both authors contributed equally.

20. Scope and limitations of the dual-gold-catalysed hydrophenoxylation of alkynes

Gómez-Suárez, A.; Oonishi, Y.; Martin, A. R.; Nolan, S. P. Beilstein J. Org. Chem. 2016, 12, 172

19. On the mechanism of the digold(I) hydroxide-catalysed hydrophenoxylation of alkynes

Gómez-Suárez, A.; Oonishi, Y.; Martin, A. R.; Vummaleti, S. V. C.; Nelson, D. J.; Cordes, D. B.; Slawin, A. M. Z.; Cavallo, L.; Nolan, S.P.; Poater, A.; Chem. Eur. J. 2016, 22, 1125

18. Gold-acetonyl complexes: from side-products to valuable synthons

Gasperini, D.; Collado, A.; Gómez-Suárez, A.; Cordes, D. B.; Slawin, A. M. Z.; Nolan, S. P. Chem. Eur. J. 2015, 21, 5403

17. What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

Vummaleti, S. V. C.; Nelson, D. J.; Poater, A.; Gómez-Suárez, A.; Cordes, D. B.; Slawin, A. M. Z.; Nolan, S. P.; Cavallo, L., Chem. Sci. 2015, 6, 1895

16. [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro-gold

Gómez-Suárez, A.; Collado, A.; Nolan, S. P In e-EROS, Electronic Encyclopedia of Reagents for Organic Synthesis; John Wiley & Sons, Ltd.: Chichester, U.K., 2014.

15. [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]chloro-gold

 

Collado, A.; Gómez-Suárez, A.; Nolan, S. P In e-EROS, Electronic Encyclopedia of Reagents for Organic Synthesis; John Wiley & Sons, Ltd.: Chichester, U.K., 2014.

14. [Au]/[Pd] multicatalytic process: direct one-pot access to benzo[c]chromenes and benzo[b]furans

Oonishi, Y.; Gómez-Suárez, A.; Martin, A. R.; Makida, Y.; Slawin, A. M. Z.; Nolan, S. P. Chem. Eur. J. 2014, 20, 13507

 

13. Trapping atmospheric CO2 with gold

Collado, A.; Gómez-Suárez, A.; Webb, P. B.; Kruger, H.; Bühl, M.; Cordes, D. B.; Slawin, A. M. Z.; Nolan, S. P. Chem. Commun. 2014, 50, 11321

12. Highly efficient and eco-friendly gold-catalyzed synthesis of homoallylic ketones

 

Gómez-Suárez, A.; Gasperini, D.; Vummaleti, S. V. C.; Poater, A.; Cavallo, L.; Nolan, S. P. ACS Catal. 2014, 2701.

11. New [Au(NHC)(OH)] complexes for silver-free protocols

 

Patrick, S. R.; Gómez-Suárez, A.; Slawin, A. M. Z.; Nolan, S. P. Organometallics 2013, 33, 421.

10. Synthesis, characterization and luminiscence studies of gold(I)-NHC amide complexes

Gómez-Suárez, A.; Nelson, D. J.; Thompson, D. G.; Cordes, D. B.; Graham, D.; Slawin, A. M. Z.; Nolan, S. P., Beilstein J. Org. Chem. 2013, 9, 2216.

9. Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

Collado, A.; Gómez-Suárez, A.; Slawin, A. M. Z.; Nolan, S. P. Chem. Commun. 2013, 49, 10745

8. Hydrophenoxylation of alkynes by cooperative gold catalysis

Oonishi, Y.; Gómez-Suárez, A.; Martin, A. R.; Nolan, S. P. Angew. Chem. Int. Ed. 2013, 52, 9767.

7. Straightforward synthesis of [Au(NHC)X] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

 

Collado, A.; Gómez-Suárez, A.; Martin, A. R.; Slawin, A. M. Z.; Nolan, S. P. Chem. Commun. 2013, 49, 5541.

6. [{Au(NHC)}2(µ-OH)][BF4]: Silver-free and acid-free catalysts for water-inclusive gold-mediated organic transformations

Gómez-Suárez, A.; Oonishi, Y.; Meiries, S.; Nolan, S. P. Organometallics, 2013, 32, 1106

5. Straightforward synthetic access to gem-diaurated and digold σ,π-acetylide species

Gómez-Suárez, A.; Dupuy, S.; Slawin, A. M. Z.; Nolan, S. P. Angew. Chem. Int. Ed. 2013, 52, 938.

4. Dinuclear gold catalysis: are two gold centers better than one?

Gómez-Suárez, A.; Nolan, S. P. Angew. Chem. Int. Ed. 2012, 51, 8156.

3. Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes

Gómez-Suárez, A.; Ramón, R. S.; Slawin, A. M. Z.; Nolan, S. P. Dalton Trans. 2012, 41, 5461

2. Influence of a very bulky N-heterocyclic carbene in gold-mediated catalysis

Gómez-Suárez, A.; Ramón, R. S.; Songis, O.; Slawin, A. M. Z.; Cazin, C. S. J.; Nolan, S. P. Organometallics 2011, 30, 5463

1. Gold(I)-catalyzed tandem alkoxylation/lactonization of γ−hydroxy-α,β-acetylenic esters

Ramón, R. S.; Pottier, C.; Gómez-Suárez, A.; Nolan, S. P. Adv. Synth. Catal. 2011, 353, 1575

Book Chapters

Metallate Complexes of the Late Transition Metals: Organometallic Chemistry and Catalysis.

Gómez-Suárez, A.; Nelson, D. J.; Nolan, S. P., Metallate Complexes of the Late Transition Metals: Organometallic Chemistry and Catalysis. In Adv. Organomet. Chem., Academic Press: 2018.

Sustainable Homogeneous gold catalysis

Collado, A.; Gómez-Suárez, A.; and Nolan, S. P.; in Sustainable catalysis: with non-endangered metals, ed. North, M., The Royal Society of Chemistry, London, 2015, vol. 2, chp. 16.